ExxonMobil, institute make discovery possibly impacting ethylene production

IRVING, Texas — Scientists from ExxonMobil and the Instituto de Tecnologia Quimica (ITQ) in Valencia, Spain have discovered a potentially revolutionary new material that could significantly reduce the amount of energy and emissions associated with the production of ethylene. Depending on the application, use of the new material, in conjunction with other novel separation processes, could result in up to a 25% reduction in both the energy needed for ethylene separation, as well as the associated carbon dioxide emissions. Results of the research have been published in the peer-reviewed journal Science.

ExxonMobil and ITQ researchers found that the new material, composed of a uniquely structured silica zeolite, can be used in gas separation processes, such as the recovery of ethylene from ethane, with an unprecedented degree of selectivity at ambient temperature. The new material could provide insights into the design of additional materials to be used as adsorbents or membranes in a variety of different gas separation applications associated with chemical manufacturing. Zeolites are porous materials frequently used as adsorbents and catalysts in chemical processes.

“Cryogenic distillation, the current commercial-scale process used for ethylene separation, is an energy-intensive process,” said Vijay Swarup, vice president of research and development at ExxonMobil Research and Engineering Company. “If advanced to commercial scale, use of this new material could significantly reduce the amount of energy and emissions associated with ethylene production. This is another great example of collaboration between industry and a university that is focused on driving solutions for improving energy efficiency and reducing carbon emissions from industrial processes.”

The patented new material, ITQ-55, is able to selectively adsorb ethylene over ethane as a result of its unique flexible pore structure. Built from heart-shaped cages interconnected by flexible elongated pore openings, the material allows the diffusion of the flatter ethylene molecules as opposed to the more cylindrical-shaped ethane molecules. The new material acts as a flexible molecular sieve.

Additional research must be conducted before the material can be considered for larger-scale demonstration and commercialization. Fundamental research will continue focusing on incorporating the material into a membrane and developing additional novel materials for gas separation.

“Our ultimate goal of actually replacing cryogenic distillation is a long-term challenge that will require many more years of research and testing, in and out of the lab,” said Gary Casty, section head for catalysis at ExxonMobil Research and Engineering Company. “Our next steps will focus on better understanding the full potential of this new zeolite material.”

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